Mercury, a nonwetting liquid, is intruded into the porous structure with increasing pressure. Porosimetry by mercury intrusion 3 differ in size from the voids, the latter can be separated by control. Mercury porosimetry is used to measure the porosity of a material by applying controlled pressure to a sample immersed in mercury. Introduction theory the measurement technique tips and tricks precision and accuracy. These articles have been written by micromeritics research and applications scientists. A typical mercury intrusion porosimetry test involves placing a sample into a container, evacuating the container to remove contaminant gases and vapors usually water and, while still evacuated, allowing mercury to fill the container. Autopore iv series mercury porosimeter 9500 and 9510. The data output is the mercury intrusion volume as a function of applied pressure, p. The autopore v series mercury porosimeters can determine a broader pore size distribution more quickly and accurately than other methods. The mercury porosimetry technique is one of the most useful methods to investigate the porous structure of solid samples in a quantitative way. Pore diameter, d, is related to the applied pressure by the washburn equation. Quantachrome offers instruments for determining pore size by gas adsorption, mercury porosimetry and capillary flow porometry. Porosimetry data were obtained using a poresizer 9320 from micromeritics.
Mercury porosimetry experiments were performed using a micromeritics autopore iv 9420. I am new in porosity analyzing techniques, but i am very interested in. One micromeritics dr, norcross, ga mechanical engineering design 9th pdf 300931877, usa. Introduction high pressure mercury porosimetry measurements have become a standard methodology to characterize both natural and manmade porous media. Overlay of bjh desorption and mercury intrusion pore size distributions. Porosimetry gas sorption, mercury intrusion, porometry porosimetry porometry measuring pore size by gas sorption, mercury intrusion, electroacoustic spectroscopy and capillary flow porometry.
The information contained herein pertains for the most part to the general technique of mercury porosimetry without regard to a specific instrument manufacturer or model. The paper describes general concepts of mercury porosimetry measurements and provides an overview on the current status of porenetwork analysis tools. Porosimetry gas sorption, mercury intrusion, porometry. Mercury porosimetry mercury porosimetry provides a wealth of information for the understanding of any porous material within the 0. Besides offering speed, accuracy, and a wide measurement range, mercury porosimetry permits you to calculate. Porosimeter autopore iv can be used for characterizing pore size ranging between 0. Besides offering speed, accuracy, and a wide measurement range, mercury porosimetry permits you to calculate numerous sample properties. Mercury intrusion porosimetry mip gas adsorption and porosimetry analytical testing for the the evaluation of porosity, pore size distribution, and pore volume among others to characterize a wide variety of solid and powder materials. Porosimetry by mercury intrusion official may 1, 2012 figure 1. This is called mercury porosimetry, or often, mercury intrusion. Class leading, proven performance autopore v mercury intrusion porosimeter the mercury porosimetry analysis technique is based on the intrusion of mercury into a porous structure under stringently controlled pressures. The mercury porosimetry analysis technique is based on the intrusion of mercury into a porous structure under stringently controlled pressures. And, micromeritics mercury porosimeters provide comprehensive data for a wide spectrum of applications.
Pharmaceuticals porosity and surface area play major roles in the purification, processing, blending, tableting, and. Micromeritics instruments, nevertheless, are no exception to the desirability for periodic performance evaluation, because detectors, like everything else, age, drift, and occasionally fail. Practical aspects of the technique are described as well as emphasizing the need for testing of model pore structures and the status on pore network modeling software. Pascal mercury porosimeters thermo fisher scientific. The pore size can be calculated by washburns equation. This instrument also features enhanced safety features and offers new data reduction and reporting choices that provide more information about pore geometry and the fluid transport characteristics of your material. Micromeritics autopore iv 9500 series characterizes a materials porosity by applying various levels of pressure to a sample immersed in mercury. A methodology for blank and conformance corrections for. It provides reliable information about pore sizevolume distribution, bulk and apparent density and specific surface for most porous materials, regardless of their nature and. Characterization of eucalypt wood by mercury porosimetry. Mercury porosimetry for porosity measurement delft. The pressure required to intrude mercury into the samples pores is inversely proportional to the size of the pores. Mercury porosimetry can determine a broader pore size distribution with greater speed and accuracy than other methods.
The pressure required to intrude mercury into the sample pores is inversely proportional to the size of the pores. In mercury porosimetry, the sample is first evacuated, then surrounded with mercury and, finally, pressure is applied to force mercury into the void spaces whilst monitoring the amount of mercury intruded. Mercury porosimetry is a popular technique which is based on the principle that the. Specific surface area information can also be derived from the mercury porosimetry measurement, but this information is much more reliable obtained from physical gas adsorption measurements using the bet analysis. Example of the setup of a mercury porosimeter instrument. The vacuum is required to ensure the transfer of mercury from the reservoir to the. Not only is mercury porosimetry applicable over a wide range of pore sizes, but also the fundamen tal data it produces the volume of mercury intruded into the. Thermo scientific pascal mercury porosimeters provide reliable information about pore sizevolume distribution, particle size distribution, bulk envelope density and speci. What is the difference between bet and mercury porosimetry. Mercury porosimetry characterizes a materials porosity by applying various levels of pressure to a sample immersed in mercury. Introduction to chemical adsorption analytical techniques. The porosimeter employed was an autopore iv 9500 from.
Autopore iv mercury porosimeter applications micromeritics. The data may be copied by rightclicking on either the cumulative or incremental pore volume graphs generated by the autopore reports and then using the copy as text option. Proven science mercury porosimetry is based on the capillary law governing liquid penetration into small pores. Micromeritics autopore iv 9510 characterizes a material porosity by applying various levels of pressure to a sample immersed in mercury. Mercury intrusion porosimetry micromeritics autopore v.
Besides offering speed, accuracy, and a wide measurement range, mercury porosimetry permits you to calculate numerous sample properties such as pore size distributions, total pore volume, total pore. Equilibrated versus scanning porosimetry micromeritics. Certified silicaalumina reference material micromeritics pn0041682200 0201 the samples were analysed using a micromeritics autopore iii 9420 mercury porosimeter which covers the pore diameter range from approximately 360 to 0. Example file format for importing mercury porosimetry data. Mercury porosimetry reference material micromeritics. The autopore v series mercury porosimeters can reportedly determine a broader pore size distribution. In addition to offering speed, accuracy, and a wide measurement range, mercury porosimetry permits the calculation of numerous sample properties such as pore size distributions, total pore volume, total pore surface area, median pore diameter and sample densities bulk and skeletal. Micromeritics, auto pore iii, mercury intrusion porosimeter. Mercury porosimetry advantages and limitations herbert giesche new york state college of ceramics at alfred university. Investigate the porous structure of solid samples quantitatively with mercury porosimetry analysis. Mercury porosimetry can determine a broader pore size distribu tion more quickly and accurately than other methods.
Autopore is primarily intended to measure the total volume of pores within a sample between an upper and lower limit of. Mercury porosimetry an overview sciencedirect topics. Porosimetry is an analytical technique used to determine materials pore structure, in particular pore size and pore size distribution, by intrusion of a liquid. Mercury porosimetry is used to measure the porosity of a. Mercury intrusion porosimetry particle technology labs. Mercury intrusion porosimetry theory micromeritics. Filling the penetrometer with mercury use mercury of analytical quality. However, micromeritics autopore series of porosimeters is used as a reference, particularly when examples are required and details of data reduction are presented. The mercury porosimetry analysis technique is based on the. An introduction to mercury porosimetry by mca services, an analytical technique for analysing the porosity, pore size and area distribution, density and permeability of solid samples. Mercury porosimetry is based on the capillary law governing liquid penetration into small spaces.
In the latter work, a mercury porosimeter micromeritics autopore iv. Mercury porosimetry is a popular technique which is based on the principle that the pressure required to force a nonwetting liquid such as mercury into pores, against the resistance of liquid surface tension, is indicative of the pore size, assuming the pores are cylindrical in shape. External pressure is required for mercury to penetrate into the pores of a material due to high contact angle of mercury. Crosssection of a drop of nonwetting liquid resting on a solid surface. Physical characterization of materials using porosimetry. What are the pros and cons of bet and mercury porosimetry in pore analysis pore size, pore volumes, pore size distribution. Mercury porosimetry of certified silicaalumina reference. Mercury porosimeter chemical engineering, iit bombay. Introduction to mercury porosimetry part 1 youtube. To perform mercury intrusion porosimetry, various levels of pressure are applied to a sample immersed in mercury a nonwetting liquid. This creates an environment consisting of a solid, a nonwetting liquid mercury, and mercury vapor. Another advantage of the mercury porosimetry analysis is the fact that you might be able to separate external from internal surface area in your particles as the technique allows one to associated.
Besides offering speed, accuracy, and a wide measurement range, mercury porosimetry permits you to calculate numerous sample. The cumulative or incremental data is available from the micromeritics autopore 9500 application. For determining the exact contact angle, micromeritics offers the contact. Data of intruded volume of mercury versus applied pressure are obtained and the pressures are converted to pore sizes using equation 2. The low and highpressure mercury intrusion porosimetry measurements can be executed on different types of mercury porosimeters. Sample data outputs from analyses including bet specific surface area, micropore, mesopore, mercury intrusion porosimetry, chemisorption, microscopy, nanotechnology, zeta potential and particle size distribution analyses. Mercury porosimetry can determine a broader pore size distribu tion more quickly. An added advantage is that porosimeter is a completely automated system. What are the pros and cons of bet and mercury porosimetry.
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